A Hydrophilic Channel Is Involved in Oxidative Inactivation of a [NiFeSe] Hydrogenase

Hydrogenases are metalloenzymes that catalyze the redox conversion between H2 and protons. The so-called [NiFeSe] hydrogenases are highly active for both H2 production and oxidation, but like all hydrogenases, they are inhibited by O2. In the [NiFeSe] enzyme from Desulfovibrio vulgaris Hildenborough...

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Bibliographic Details
Main Author: Zacarias, Sónia (author)
Other Authors: Temporão, Adriana (author), Barrio, Melisa Del (author), Fourmond, Vincent (author), Léger, Christophe (author), Matias, Pedro M. (author), Pereira, Inês A.C. (author)
Format: article
Language:eng
Published: 2019
Subjects:
hydrogen
hydrogenases
hydrophilic channel
selenium
sulfenate
sulfinate
Catalysis
Chemistry(all)
Online Access:http://hdl.handle.net/10362/91637
Country:Portugal
Oai:oai:run.unl.pt:10362/91637

Internet

http://hdl.handle.net/10362/91637

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