Catalytic cyclization of propargyl bromoethers via electrogenerated nickel(I) tetramethylcyclam in Ionic liquids: water effects

Cyclic voltammetry and controlled-potential electrolysis have been employed to investigate the reductive intramolecular cyclization of propargyl bromoethers derivatives, catalyzed by electrogenerated (1,4,8,11-tetramethyl-1,4,8,11-tetraaza-cyclotetradecane) nickel(I), [Ni(tmc)](+), as the catalyst,...

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Bibliographic Details
Main Author: Mendes, Jorge António Silva (author)
Other Authors: Duñach, E. (author), Esperanca, J. M. S. S. (author), Medeiros, Maria José (author), Ribeiro, J. F. (author), Silva, Maria Manuela (author), Olivero, S. (author)
Format: article
Language:eng
Published: 2019
Subjects:
Room temperature ionic liquids
Electroreduction
Intramolecular cyclization
Nickel(I) tetramethylcyclam
Bromopropargyloxy ester
Science & Technology
Online Access:http://hdl.handle.net/1822/73059
Country:Portugal
Oai:oai:repositorium.sdum.uminho.pt:1822/73059

Internet

http://hdl.handle.net/1822/73059

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