Catalytic olefin epoxidation with a carboxylic acid-functionalized cyclopentadienyl molybdenum tricarbonyl complex

The complex CpMo(CO)(3)CH2COOH (1) (Cp = eta(5)-C5H5) has been examined as a precatalyst for the epoxidation of cis-cyclooctene and alpha-pinene using tert-butylhydroperoxide (TBHP) as oxidant. A high turnover frequency of ca. 600 mol mol(Mo)(-1) h(-1) was achieved in the epoxidation of cyclooctene,...

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Bibliographic Details
Main Author: Gomes, Ana C. (author)
Other Authors: Bruno, Sofia M. (author), Abrantes, Marta (author), Magalhaes, Clara I. R. (author), Goncalves, Isabel S. (author), Valente, Anabela A. (author), Pillinger, Martyn (author)
Format: article
Language:eng
Published: 1000
Subjects:
LAYERED DOUBLE HYDROXIDE
ETA(5)-CYCLOPENTADIENYL MOLYBDENUM
TUNGSTEN COMPLEXES
CYCLOALKYL MOIETIES
INCLUSION-COMPOUNDS
CARBONYL-COMPLEXES
CRYSTAL-STRUCTURE
OXO-MOLYBDENUM
BRIDGING UNITS
ANSA COMPOUNDS
Online Access:http://hdl.handle.net/10773/19339
Country:Portugal
Oai:oai:ria.ua.pt:10773/19339

Internet

http://hdl.handle.net/10773/19339

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