The chapman-type rearrangement in pseudosaccharins: the case of 3-(methoxy)-1,2-benzisothiazole 1,1-dioxide

The thermal Chapman-type rearrangement of the pseudosaccharin 3-(methoxy)-1,2-benzisothiazole 1,1-dioxide (MBID) into 2-methyl-1,2-benzisothiazol-3(2H)-one 1,1-dioxide (MBIOD) was investigated on the basis of computational models and knowledge of the structure of the reactant and product in the isol...

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Bibliographic Details
Main Author: Kaczor, A. (author)
Other Authors: Proniewicz, L. M. (author), Almeida, R. (author), Gómez-Zavaglia, A. (author), Cristiano, Maria Lurdes Santos (author), Matos Beja, A. M. (author), Ramos Silva, M. (author), Fausto, R. (author)
Format: article
Language:eng
Published: 2014
Subjects:
Pseudosaccharyl ether
Molecular structure
Reaction path
IR spectra
Matrix-isolation
DFT calculations
Online Access:http://hdl.handle.net/10400.1/4254
Country:Portugal
Oai:oai:sapientia.ualg.pt:10400.1/4254

Internet

http://hdl.handle.net/10400.1/4254

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