Reaction of aromatic nitroso compounds with chemical models of thiamin active aldehyde

Aromatic nitroso compounds in the presence of base and 2-(a-hydroxyalkyl)-3,4-dimethylthiazolium trifluoromethanesulfonate and related salts furnish in variable yields O- and N-acyl-aryl hydroxylamines and 3,4-dimethylthiazolium trifluoromethanesulfonate. A primary kinetic isotope effect of 4.9, obt...

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Bibliographic Details
Main Author: Ferreira, L. M. (author)
Other Authors: Marques, M. M. B. (author), Glória, P. M. C. (author), Chaves, Humberto (author), Franco, J. P. P. (author), Mourato, I. (author), Antunes, J. R. T (author), Rzepa, H. S. (author), Prabhakar, S. (author)
Format: article
Language:eng
Published: 2020
Subjects:
Aromatic Nitroso Compounds
Theoretical calculations
Thiazolium salts
Thiamine
Online Access:http://hdl.handle.net/20.500.12207/5204
Country:Portugal
Oai:oai:repositorio.ipbeja.pt:20.500.12207/5204

Internet

http://hdl.handle.net/20.500.12207/5204

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