Crystal Structure and Catalytic Behavior in Olefin Epoxidation of a One-Dimensional Tungsten Oxide/Bipyridine Hybrid

The tungsten oxide/2,2'-bipyridine hybrid material [WO3(2,2'-bpy)]center dot nH(2)O (n = 1-2) (1) has been prepared in near quantitative yield by the reaction of H2WO4, 2,2'-bpy, and H2O in the mole ratio of ca. 1:2:700 at 160 degrees C for 98 h in a rotating Teflon-lined digestion bo...

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Bibliographic Details
Main Author: Amarante, Tatiana R. (author)
Other Authors: Antunes, Margarida M. (author), Valente, Anabela A. (author), Almeida Paz, Filipe A. (author), Pillinger, Martyn (author), Goncalves, Isabel S. (author)
Format: article
Language:eng
Published: 1000
Subjects:
HYDROTHERMAL SYNTHESIS
CYCLOOCTENE EPOXIDATION
MOLECULAR MANIPULATION
MOLYBDENUM OXIDES
OPEN-FRAMEWORKS
COMPLEXES
LIGANDS
MO
PRECURSORS
NETWORK
Online Access:http://hdl.handle.net/10773/20733
Country:Portugal
Oai:oai:ria.ua.pt:10773/20733

Internet

http://hdl.handle.net/10773/20733

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