Structure and Dynamics of Lanthanide Complexes of Triethylenetetramine-N,N,N',N'',N''',N'''-hexaacetic Acid (H6ttha) and of Diamides H4ttha(NHR) Derived from H6ttha as Studied by NMR, NMRD, and EPR

A multinuclear NMR study on [Ln(ttha)]3- and [Ln{ttha(NHR)2}]- complexes (R=Et, CH2(CHOH)4CH2OH) shows that coordinating groups of the organic ligands in these complexes are occupying all coordination sites of the metal ions, leaving no space for coordination of H2O molecules (H6ttha=triethylenetetr...

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Detalhes bibliográficos
Autor principal: Zitha-Bovens, Emrin (author)
Outros Autores: Muller, Robert N. (author), Laurent, Sophie (author), Vander Elst, Luce (author), Geraldes, Carlos F. G. C. (author), van Bekkum, Herman (author), Peters, Joop A. (author)
Formato: article
Idioma:eng
Publicado em: 2005
Texto completo:http://hdl.handle.net/10316/8125
País:Portugal
Oai:oai:estudogeral.sib.uc.pt:10316/8125