Compromise between conjugation length and charge-transfer in nonlinear optical η5-monocyclopentadienyliron(II) complexes with substituted oligo-thiophene nitrile ligands: synthesis, electrochemical studies and first hyperpolarizabilities
A systematic series of η5-monocyclopentadienyliron(II) complexes with substituted oligo-thiophene nitrile ligands of general formula [FeCp(P_P)(NC{SC4H2}nNO2)][PF6] (P_P=dppe, (+)-diop; n=1-3) has been synthesized and characterized. The electrochemical behaviour of the new compounds was explored by...
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| Formato: | article |
| Idioma: | eng |
| Publicado em: |
2008
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| Texto completo: | http://hdl.handle.net/10174/1061 |
| País: | Portugal |
| Oai: | oai:dspace.uevora.pt:10174/1061 |