New RuII(arene) complexes with halogen-substituted bis- and tris(pyrazol-1-YL)borate ligands

[RuCl(arene)(-Cl)](2) dimers were treated in a 1:2 molar ratio with sodium or thallium salts of bis- and tris(pyrazolyl)borate ligands [Na(BpBr3)], [Tl(TpBr3)], and [Tl(Tp(iPr,4Br))]. Mononuclear neutral complexes [RuCl(arene)((2)-BpBr3)] (1: arene=p-cymene (cym); 2: arene=hexamethylbenzene (hmb); 3...

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Detalhes bibliográficos
Autor principal: Orbisaglia, Serena (author)
Outros Autores: Di Nicola, Corrado (author), Marchetti, Fabio (author), Pettinari, Riccardo (author), Martins, Luisa (author), Alegria, Elisabete (author), Guedes Da Silva, M. Fátima C. (author), Rocha, Bruno G. M. (author), Kuznetsov, Maxim L. (author), Pombeiro, Armando (author), Skelton, Brian (author), Sobolev, Alexandre (author), White, Allan H. (author)
Formato: article
Idioma:eng
Publicado em: 2015
Assuntos:
Arenes
Borates
Density functional calculations
Ligands
Ruthenium
Texto completo:http://hdl.handle.net/10400.21/4952
País:Portugal
Oai:oai:repositorio.ipl.pt:10400.21/4952

Texto Completo

http://hdl.handle.net/10400.21/4952

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