A bis(mu-chlorido)-bridged cobalt(II) complex with silyl-containing schiff base as a catalyst precursor in the solvent-free oxidation of cyclohexane

A new bis(µ-chlorido)-bridged cobalt(II) complex [Co2(µ-Cl)2(HL2)4][CoCl4] (1), where HL2 is a silyl-containing Schiff base, was synthesised. The structure of this compound was established by X-ray crystallography revealing a zwitterionic form adopted by the organic ligand. The temperature dependenc...

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Bibliographic Details
Main Author: Zaltariov, Mirela-Fernanda (author)
Other Authors: Vieru, Veacheslav (author), Zalibera, Michal (author), Cazacu, Maria (author), Martins, Nuno M. R. (author), Martins, Luisa (author), Rapta, Peter (author), NOVITCHI, Ghenadie (author), Shova, Sergiu (author), Pombeiro, Armando (author), Arion, Vladimir B. (author)
Format: article
Language:eng
Published: 2017
Subjects:
Cobalt
Silicon
Schiff bases
Catalyst precursors
Oxidation
Cyclohexane
Online Access:http://hdl.handle.net/10400.21/7482
Country:Portugal
Oai:oai:repositorio.ipl.pt:10400.21/7482

Internet

http://hdl.handle.net/10400.21/7482

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