Sol-gel derived lanthanide-substituted layered double hydroxides Mg3/Al1-xLnx

Mg/Al/Ln (Ln = Nd, Sm, Eu) layered double hydroxides (LDHs) were synthesized using sol–gel method for the first time to the best our knowledge. The obtained materials were characterized by X-ray di raction analysis and fluorescence spectroscopy. The phase composition and luminescent properties of th...

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Detalhes bibliográficos
Autor principal: Smalenskaite, A. (author)
Outros Autores: Şen, S. (author), Salak, A.N. (author), Ferreira, M. G. S. (author), Beganskiene, A. (author), Kareiva, A. (author)
Formato: article
Idioma:eng
Publicado em: 2019
Assuntos:
Layered double hydroxides
Sol-gel processing
Luminescent properties
Texto completo:http://hdl.handle.net/10773/25383
País:Portugal
Oai:oai:ria.ua.pt:10773/25383
Descrição
Resumo:Mg/Al/Ln (Ln = Nd, Sm, Eu) layered double hydroxides (LDHs) were synthesized using sol–gel method for the first time to the best our knowledge. The obtained materials were characterized by X-ray di raction analysis and fluorescence spectroscopy. The phase composition and luminescent properties of these LDHs were investigated and discussed. The Ln3+ substitution e ects were investigated in the Mg3Al1−xLnx LDHs by changing the Ln3+ concentration in the metal cation layers up to 10 mol%. It was demonstrated that only Mg3Al1−xEux LDHs showed luminescence properties, however, no any light emission was observed for the Mg3Al1−xNdx and Mg3Al1−xSmx LDH samples

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