Partial replacement of EPR by GTR in highly flowable PP/EPR blends: Effects on morphology and mechanical properties

This research analyzes the effect of ground tire rubber (GTR) and a novel metallocene-based ethylene–propylene copolymer (EPR), with high propylene content, on the morphology and mechanical behavior of ternary polymer blends based on a highly flowable polypropylene homopolymer (PP). The PP/EPR blend...

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Bibliographic Details
Main Author: Lima, Paulo Silva (author)
Other Authors: Oliveira, Jose Martinho (author), Costa, V.A.F. (author)
Format: article
Language:eng
Published: 2015
Subjects:
Online Access:http://hdl.handle.net/10773/16355
Country:Portugal
Oai:oai:ria.ua.pt:10773/16355
Description
Summary:This research analyzes the effect of ground tire rubber (GTR) and a novel metallocene-based ethylene–propylene copolymer (EPR), with high propylene content, on the morphology and mechanical behavior of ternary polymer blends based on a highly flowable polypropylene homopolymer (PP). The PP/EPR blends morphology, with very small domains of EPR dispersed in the PP matrix, indicates a good compatibility among these materials, which leads to a significant improvement on elongation at break and impact strength. The incorporation of EPR on the rubber phase of thermoplastic elastomeric blends (TPE) based on GTR and PP (TPEGTR) has a positive effect on their mechanical performance, attributed to the toughness enhancement of the PP matrix and to the establishment of shell-core morphology between the rubber phases. The mechanical properties of the ternary blends reveal that TPEGTR blends allow the upcycling of this GTR material by injection molding technologies.