On the chemical reactions of carbon dioxide isoelectronic molecules CS2 and OCS with 1-butyl-3-methylimidazolium acetate

Raman and NMR spectroscopies show that CS2 and OCS react spontaneously with 1-butyl-3-methylimidazolium acetate [C(4)mim] [Ac] in the liquid phase. The formation of [C(4)mim] CO2, [C(4)mim] COS, CH3COS- and gaseous CO2 and OCS in both systems demonstrates that the anion plays an unexpected role not...

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Detalhes bibliográficos
Autor principal: Isabel Cabaco, M. (author)
Outros Autores: Besnard, Marcel (author), Chavez, Fabian Vaca (author), Pinaud, Noel (author), Sebastiao, Pedro J. (author), Coutinho, Joao A. P. (author), Mascetti, Joelle (author), Danten, Yann (author)
Formato: article
Idioma:eng
Publicado em: 1000
Assuntos:
IONIC LIQUIDS
CO2
SULFIDE
DITHIOCARBOXYLATES
COMPLEXES
SYSTEMS
PHASE
Texto completo:http://hdl.handle.net/10773/20498
País:Portugal
Oai:oai:ria.ua.pt:10773/20498

Texto Completo

http://hdl.handle.net/10773/20498

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