Thienylpyrrole azo dyes: synthesis, solvatochromic and electrochemical properties

The synthesis and the evaluation of solvatochromic and electrochemical properties of new donor-acceptor-substituted thienylpyrrole azo dyes 3 are described. These derivatives exhibit dramatic changes in both their electronic and redox properties in comparison with thienylpyrroles 1. In agreement wit...

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Bibliographic Details
Main Author: Raposo, M. Manuela M. (author)
Other Authors: Sousa, Ana M. R. C. (author), Fonseca, A. Maurício C. (author), Kirsch, G. (author)
Format: article
Language:eng
Published: 2005
Subjects:
Online Access:http://hdl.handle.net/1822/7838
Country:Portugal
Oai:oai:repositorium.sdum.uminho.pt:1822/7838
Description
Summary:The synthesis and the evaluation of solvatochromic and electrochemical properties of new donor-acceptor-substituted thienylpyrrole azo dyes 3 are described. These derivatives exhibit dramatic changes in both their electronic and redox properties in comparison with thienylpyrroles 1. In agreement with the solvatochromic and electrochemical studies of push-pull derivatives 3 the new compounds prepared, may find application in the manufacture of new materials with notable non-linear optical properties.