Diffusion coefficients in aqueous solutions of potassium sulfocyanate at 298.15 K

Differential diffusion coefficients of potassium sulfocyanate in water at 298.15 K, and at concentrations from 0.001 M to 1 M, have been measured using a conductimetric cell and an automatic apparatus to follow diffusion. The results are discussed on the basis of the Onsager-Fuoss and Pikal models....

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Detalhes bibliográficos
Autor principal: Ribeiro, Ana C. F. (author)
Outros Autores: Lobo, Victor M. M. (author), Natividade, Joaquim J. S. (author)
Formato: article
Idioma:eng
Publicado em: 2001
Assuntos:
Texto completo:http://hdl.handle.net/10316/5205
País:Portugal
Oai:oai:estudogeral.sib.uc.pt:10316/5205
Descrição
Resumo:Differential diffusion coefficients of potassium sulfocyanate in water at 298.15 K, and at concentrations from 0.001 M to 1 M, have been measured using a conductimetric cell and an automatic apparatus to follow diffusion. The results are discussed on the basis of the Onsager-Fuoss and Pikal models. The cell uses an open-ended capillary method and a conductimetric technique is used to follow the diffusion process by measuring the resistance of a solution inside the capillaries, at recorded times.