Electroreductive intramolecular cyclization of bromoalkoxylated derivatives catalyzed by nickel(I) tetramethylcyclam in "green" media

The (1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetra-decane)nickel(I), [Ni(tmc)]+, electrogenerated at glassy carbon cathodes is shown to be an effective catalyst for the intramolecular radical-type cyclisation of bromoalkoxylated derivatives 1 in alcohol and / or alcohol/water mixtures as well as...

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Bibliographic Details
Main Author: Medeiros, M. J. (author)
Other Authors: Neves, C. S. S. (author), Pereira, A. R. (author), Duñach, E. (author)
Format: article
Language:eng
Published: 2011
Subjects:
Microemulsions
Electrosynthesis
Catalytic reduction
Intramolecular cyclisation
Nickel(II) complex
Online Access:http://hdl.handle.net/1822/13442
Country:Portugal
Oai:oai:repositorium.sdum.uminho.pt:1822/13442

Internet

http://hdl.handle.net/1822/13442

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