Synthesis of fluorescent alanines by a rhodium catalysed conjugate addition of arylboronic acids to dehydroalanine derivatives

Several arylalanine derivatives containing fluorescent groups were prepared in good yields using a rhodium catalysed conjugate addition of arylboronic acids to N,N-diprotected and N-monoprotected dehydroalanines. The best conditions for these reactions require the use of an excess of aryl boronic ac...

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Bibliographic Details
Main Author: Ferreira, Paula M. T. (author)
Other Authors: Monteiro, Luís S. (author), Castanheira, Elisabete M. S. (author), Pereira, Goreti (author), Frost, Christopher G. (author)
Format: article
Language:eng
Published: 2013
Subjects:
Dehydroalanines
Rhodium-catalysis
Arylboronic acids
Conjugate addition
Fluorescent marker
Amino acids
Rhodium
Homogeneous catalysis
Fluorescent probes
Science & Technology
Online Access:http://hdl.handle.net/1822/22066
Country:Portugal
Oai:oai:repositorium.sdum.uminho.pt:1822/22066

Internet

http://hdl.handle.net/1822/22066

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