Mature landfill leachate treatment by denitrification and ozonation

The removal of nitrate from a mature landfill leachate with high nitrate load in a lab-scale anoxic rotating biological contactor (RBC) was studied. Under a phosphorus-phosphate concentration of 10mg P-PO4 3− L−1 and nitrogen-nitrate concentrations above 530mgN-NO3 − L−1 the reactor achieved nitroge...

Full description

Bibliographic Details
Main Author: Cortez, Susana (author)
Other Authors: Teixeira, P. (author), Oliveira, Rosário (author), Mota, M. (author)
Format: article
Language:eng
Published: 2011
Subjects:
Online Access:http://hdl.handle.net/1822/11316
Country:Portugal
Oai:oai:repositorium.sdum.uminho.pt:1822/11316
Description
Summary:The removal of nitrate from a mature landfill leachate with high nitrate load in a lab-scale anoxic rotating biological contactor (RBC) was studied. Under a phosphorus-phosphate concentration of 10mg P-PO4 3− L−1 and nitrogen-nitrate concentrations above 530mgN-NO3 − L−1 the reactor achieved nitrogennitrate removal efficiencies close to 100%, without nitrite or nitrous oxide accumulation. Although the reactor presented a very good denitrification performance, the effluent carbon concentration was still above the legal discharge value. In order to increase the biodegradability of the leachate recalcitrant carbon load, a pre-ozonation was further investigated. The pre-ozonation led to a total organic carbon (TOC) removal of 28%. The sequence of treatments, leachate ozonation followed by RBC denitrification did not affect the denitrification efficiency. In fact, it was possible to attain a denitrification rate of 123mg N-NO3 − L−1 h−1. The moderate decrease in the carbon load of the final effluent indicated that some recalcitrant compounds were still present after ozonation. The anoxic RBC showed to be a promising technology for removing nitrate from landfill leachate.