Diels–alder reactions of alkyl 2H-azirine-3-carboxylates with furans

Methyl 2-(2,6-dichlorophenyl)-2H-azirine-3-carboxylate 1 and furan give the aziridine 2 by a Diels–Alder cycloaddition reaction. The hydrolysis of compound 2 leads to a dihydrofuranol 11 by cleavage of a C–N bond. X-Ray crystal structures of compounds 2 and 11 have been determined. Compound 2 reacts...

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Bibliographic Details
Main Author: Alves, M. José (author)
Other Authors: Azóia, Nuno G. (author), Bickley, Jamie F. (author), Fortes, A. Gil (author), Gilchrist, Thomas L. (author), Mendonça, Ricardo (author)
Format: article
Language:eng
Published: 2001
Subjects:
Online Access:https://hdl.handle.net/1822/2181
Country:Portugal
Oai:oai:repositorium.sdum.uminho.pt:1822/2181