THE SYMMETRY BREAKING PHENOMENON IN 1,2,3-TRIOXOLENE AND C2Y3Z2 (Z= O, S, Se, Te, Z= H, F) COMPOUNDS: A PSEUDO JAHN-TELLER ORIGIN STUDY

1,2,3-Trioxolene (C2O3H2) is an intermediate in the acetylene ozonolysis reaction which is called primary ozonide intermediate. The symmetry breaking phenomenon were studied in C2O3H2 and six its derivatives then oxygen atoms of the molecule are substituted by sulphur, selenium, tellurium (C2Y3H2) a...

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Bibliographic Details
Main Author: Ilkhani,Ali Reza (author)
Format: article
Language:eng
Published: 2017
Subjects:
symmetry breaking in five-member rings
PJTE
1,2,3-trioxolene derivatives
non-planarity in rings
vibronic coupling constant
Online Access:http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422017000500491
Country:Brazil
Oai:oai:scielo:S0100-40422017000500491

Internet

http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422017000500491

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