Influence of the medium (strongly acid or basic) over the electrochemical properties of the nitrate selective electrode
A nitrate selective electrode was prepared for use in an aggresive medium (high acidic or basic concentration). It is demonstrated that the depending E graph with respect to pNO3- has not a Nernstian response in concentration acidic range upper 0.1 mol/L H2SO4. The observed behaviour is supposed to...
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| Other Authors: | , , |
| Format: | article |
| Language: | eng |
| Published: |
1997
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| Subjects: | |
| Online Access: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46701997000100003 |
| Country: | Brazil |
| Oai: | oai:scielo:S0100-46701997000100003 |
| Summary: | A nitrate selective electrode was prepared for use in an aggresive medium (high acidic or basic concentration). It is demonstrated that the depending E graph with respect to pNO3- has not a Nernstian response in concentration acidic range upper 0.1 mol/L H2SO4. The observed behaviour is supposed to be due to the formation of a dimeric anion HN2O6-. |
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