Aplicação e modificação química da sílica gel obtida de areia

The silica gel was obtained from sand and its surface was modified with POCl3 to produce Si-Cl bonds on the silica surface. Ethylenediamine was covalently bonded onto the chlorinated silica surface. The adsorption of the chlorides of divalent cobalt, nickel and copper was qualitatively studied to sh...

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Bibliographic Details
Main Author: Prado, Alexandre Gustavo Soares do (author)
Other Authors: Faria, Elaine Alves de (author), Padilha, Pedro M. (author)
Format: article
Language:por
Published: 2017
Subjects:
Online Access:https://doi.org/PRADO, Alexandre G. S.; FARIA, Elaine A.; Padilha, Pedro M. Aplicação e modificação química da sílica gel obtida de areia. Química Nova, v. 28, n. 3, p. 544-547, 2005. DOI: https://doi.org/10.1590/S0100-40422005000300030. Disponível em: https://www.scielo.br/j/qn/a/W56jy53HjpWCnG3BBwc4jRH/?lang=pt#. Acesso em: 10 ago. 2021.
https://doi.org/https://dx.doi.org/10.1590/S0100-40422005000300030
Country:Brazil
Oai:oai:repositorio.unb.br:10482/26353
Description
Summary:The silica gel was obtained from sand and its surface was modified with POCl3 to produce Si-Cl bonds on the silica surface. Ethylenediamine was covalently bonded onto the chlorinated silica surface. The adsorption of the chlorides of divalent cobalt, nickel and copper was qualitatively studied to show that the bonding of ethylenediamine onto the silica gel surface produces a solid base capable of chelating metal ions from solution. The experiments illustrate the extraction of silica gel, its reactivity, the development of modified surfaces and its application in removing metal ions from water and are deigned for undergraduate inorganic chemistry laboratories.